Spent a little more time on this and now see that the server was originally configured with the drives on the highest IDs on the scsi backup plane. Any additional drives pickup lower IDs and the card attempts to boot from these.
I'm going to have to break the mirror, move the drives down the backplane and recreate the mirror.
A little worried about deleting the array as the adaptec storage manager tells me that deleting the array will delete all data. I'm sure it won't but any advise would be helpful.
(c)David Overton 2006-23